Crystal Growth of IRMOF-3 (Isoreticular Metal-Organic Frameworks-3) Synthesized using Solvothermal Method
نویسندگان
چکیده
منابع مشابه
Exceptional negative thermal expansion in isoreticular metal-organic frameworks.
The thermal-expansion properties of substances are very important in materials design; for example, cracks form when joined materials expand or contract by different amounts upon heating. The most famous example of a substance that contracts when heated is ice: it transforms into water, which has a higher density than ice. Negative thermal expansion (NTE) in solids is relatively rare, although ...
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Metal−organic frameworks (MOFs), a class of porous materials, are of particular interest in gas storage and separation applications due largely to their high internal surface areas and tunable structures. MOF-5 is perhaps the archetypal MOF; in particular, many isoreticular analogues of MOF-5 have been synthesized, comprising alternative dicarboxylic acid ligands. In this contribution we introd...
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A novel class of metal organic frameworks (MOFs) has been synthesized from Cu-acetate and dicarboxylic acids using liquid phase epitaxy. The SURMOF-2 isoreticular series exhibits P4 symmetry, for the longest linker a channel-size of 3 × 3 nm(2) is obtained, one of the largest values reported for any MOF so far. High quality, ab-initio electronic structure calculations confirm the stability of a...
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ژورنال
عنوان ژورنال: IPTEK Journal of Proceedings Series
سال: 2014
ISSN: 2354-6026
DOI: 10.12962/j23546026.y2014i1.416